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沈小平
时间:2010-04-27 13:56:51   作者:   来源:    点击:

沈小平,男,江苏省溧阳市人 , 现任江苏大学教授、博士生导师,化学系主任,无机化学硕士点方向带头人。 1992年苏州大学物理化学专业研究生毕业,获理学硕士学位;2005年南京大学无机化学专业博士研究生毕业,获理学博士学位。 曾作为访问学者分别于1997年在南京大学配位化学国家重点实验室、 2008 年在澳大利亚 University of Wollongong 进修深造各一年。多年来主要从事配合物功能材料和新型 纳米材料的研究工作,曾先后主持和参加江苏省自然科学基金项目两项( BK2005056 , BK2009196 ),国家自然科学基金项目三项( 20875039, 20371026, 20571040),国家自然科学基金重大项目一项( 20391001 ),以及江苏省高校自然科学基金( 01KJB150010 )、国家及省重点实验室开放基金等科研课题。已在 Journal of Materials Chemistry Journal of Physical Chemistry C, Carbon, Nanotechnology, Electrochemistry Communications 等国际著名学术刊物和国内核心期刊发表论文80余篇,其中SCI收录68篇, 论文已被SCI源期刊引用285篇次。有关科研成果获2005年镇江市科技进步二等奖(排名第一)和镇江市第六、七、八和九届优秀科技论文一等奖。

 

主要研究方向

•  纳米材料化学: 主要研究金属氧化物、金属硫化物、功能性配位化合物、石墨烯 - 无机(有机)复合物等的纳米材料 形状、尺寸的控制合成 和组装,研究材料 的光电磁性质 及在锂离子电池、气体传感器和催化等方面的应用 。

•  功能性配合物:研究分子基磁性材料、多孔贮氢材料等各种新颖配合物的合成和晶体结构,研究材料的磁性和吸附 - 脱附性能,探讨材料结构与性质的构效关系。

近年发表的主要论文

 

1. Xiaoping Shen* , Shikui Wu, Yan Liu, Kun Wang, Zheng Xu, Wei Liu, Morphology syntheses and properties of well-defined Prussian Blue nanocrystals by a facile solution approach, Journal of Colloid and Interface Science , 2009 , 329 (1), 188-195.

2. Xiaoping Shen* , Gui Yin, Cuiling Gao, Zheng Xu, Construction and fluorescence of organic nanotube arrays by template-based physical vapor deposition method, Materials Chemistry and Physics , 2009 , 113 (1), 202-207.

3. Xiaoping Shen* , Hui Zhao, He-Qing Shu, Hu Zhou, Ai-Hua Yuan, Self-assembly of CuS nanoflakes into flower-like microspheres: Synthesis and characterization, Journal of Physics and Chemistry of Solids , 2009 , 70 (2), 422-427.

4. Yan Xu, Xiaoping Shen* , Qian Zhang, Ai-Hua Yuan, Hu Zhou, Cyanide-bridged FeIII-MnIII bimetallic chain derived from [Fe(bipy)(CN) 4 ] - : synthesis, structure and magnetic characteristics, Journal of Coordination Chemistry , 2009 , 62(19), 3126-3133.

5. Shikui Wu, Xiaoping Shen* , Zheng Xu, Jili Wu, Cuiling Gao, Microrods based on nanocubes of Prussian blue, Applied Surface Science , 2009 , 255(22), 9182-9185.

6. Ji-Quan Sun, Xiaoping Shen* , Li-Jun Guo, Kang-Min Chen, Qi Liu, Microwave-assisted synthesis of flower-like PbS crystals, Physica E : Low-Dimensional Systems & Nanostructures , 2009 , 41(8), 1527-1532.

7. Guoxiu Wang, Xiaoping Shen , Jane Yao, Jinsoo Park, Graphene nanosheets for enhanced lithium storage in lithium ion batteries, Carbon , 2009 , 47 (8), 2049-2053.

8. Yan Xu, Hu Zhou, Ai-Hua Yuan, Xiaoping Shen* , Qian Zhang, A cyanide-bridged Fe-II-Nd-III bimetallic assembly with a one-dimensional ladder-like chain structure, Acta Crystallographica Section C , 2009 , 65, M177-M179.

9. Guoxiu Wang, Xiaoping Shen , Jane Yao, One-dimensional nanostructures as electrode materials for lithium-ion batteries with improved electrochemical performance, Journal of power Sources , 2009 , 189 (1), 543-546.

10. Guoxiu Wang, Xiaoping Shen , Bei Wang, Jane Yao, Jinsoo Park, Synthesis and characterisation of hydrophilic and organophilic graphene nanosheets, Carbon , 2009 , 47 (5), 1359-1364.

11. Yan Xu, Xiaoping Shen* , Hu Zhou, He-Qing Shu, Wenxian Li, Ai-Hua Yuan, Synthesis, crystal structure and magnetic properties of a cyanide-bridged Fe-III-Mn-III bimetallic chain based on [Fe(bipy)(CN)(4)](-) building block, Journal of Molecular Structure , 2009, 921 (1-3), 341-345.

12. Guoxiu Wang, Xiaoping Shen , Jane Yao, David Wexler, Jung-ho Ahn, Hydrothermal synthesis of carbon nanotube/cobalt oxide core-shell one-dimensional nanocomposite and application as an anode material for lithium-ion batteries, Electrochemistry Communications , 2009 , 11 (3), 546-549.

13. Jinsoo Park, Xiaoping Shen , Guoxiu Wang, Solvothermal synthesis and gas-sensing performance of Co3O4 hollow nanospheres, Sensors and Actuators B-Chemical , 2009 , 136 (2), 494-498.

14. Guoxiu Wang, Xiaoping Shen , Josip Horvat, Bei Wang, Hao Liu, David Wexler, Jane Yao, Hydrothermal Synthesis and Optical, Magnetic, and Supercapacitance Properties of Nanoporous Cobalt Oxide Nanorods, Journal of Physical Chemistry C , 2009 , 113 (11), 4357-4361.

15. Jane Yao, Xiaoping Shen , Bei Wang, Huakun Liu and Guoxiu Wang, In situ chemical synthesis of SnO 2 –graphene nanocomposite as anode materials for lithium-ion batteries, Electrochemistry Communications , 2009 , DOI:10.1016/j.elecom.2009.07.035.

16. Shikui Wu, Xiaoping Shen , Baosen Cao, Li Lin, Kecheng Shen and Wei Liu, Shape- and size-controlled synthesis of coordination polymer {[Cu(en) 2 ][KFe(CN) 6 ]} n nano/micro-crystals, Journal of Materials Science , 2009 , DOI: 10.1007/s10853-009-3864-2.

17. Xiaoping Shen * , Yan Xu, Hu Zhou, He-Qing Shu, Ai-Hua Yuan, Crystal structure and magnetic properties of a cyano-bridged bimetallic assembly [CuL] 3 [Fe(CN) 6 ] 2 × 2H 2 O (L = 3,10-dibutyl-1,3,5,8,10,12-hexaazacyclotetradecane), Journal of Molecular Structure , 2008 , 892, 58–62.

18. Shikui Wu, Wei Liu, Xiaoping Shen* , Chunyan Shi, Honghong Xu, Synthesis of Cd-II-4,4'-bipy coordination polymer nanorods with tunable size and shape, Physica E: Low-Dimensional Systems & Nanostructures, 2008, 41, 101-105.

19. Ji-Quan Sun, Xiaoping Shen* , Kang-Min Chen, Qi Liu, Wei Liu, Low-temperature synthesis of hexagonal ZnS nanoparticles by a facile microwave-assisted single-source method, Solid State Communications , 2008 , 147, 501-504.

20. Xiaoping Shen* , Hua-Juan Miao, Hui Zhao, Zheng Xu, Synthesis, characterization and magnetic properties of Co 3 O 4 nanotubes, Applied Physics A-Materials Science & Processing , 2008 , 91, 47-51.

21. Ai-hua Yuan, Xiaoping Shen , Hu Zhou, Crystal structure and magnetic properties of a three-dimensional complex constructed from [CuL](2+) and [Fe(CN)(6)](3-) precursors, Transition Metal Chemistry, 2008 , 33, 133-136.

22. Xiaoping Shen* , Shikui Wu, Hui Zhao, Qi Liu, Synthesis of single-crystalline Bi 2 O 3 nanowires by atmospheric pressure chemical vapor deposition approach, Physica E: Low-Dimensional Systems & Nanostructures, 2007, 39, 133-136.

23. Hu Zhou, Ai-Hua Yuan, Xiaoping Shen , Ying-Ying Chen, David J. Price, Cameron J. Kepert, Synthesis, crystal structure and magnetic properties of a three-dimensional cyano-bridged heterometallic complex {Ni-II(Me-6-[14]ane-N-4)} (2)[W-IV(CN)(8)] center dot 6H(2)O, Inorganic Chemistry Communications , 2007 , 10 (8), 940-943.

24. Xiaoping Shen , Zhiyuan Jiang, Cuiling Gao, Zheng Xu, Zhaoxiong Xie, Lansun Zheng , One-step construction of ZnS/C and CdS/C one-dimensional core-shell nanostructures, Journal of Materials Chemistry , 2007 , 17 , 1326-1330.

25. Xiaoping Shen , Yizhi Li, You Song, Zheng Xu, and Guocong Guo, Single crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn[Mn 0.2 Cr 0.8 (CN) 6 ] × 4H 2 O, European Journal of Inorganic Chemistr y, 2007 , 1698-1702 .

26. Xiaoping Shen , Gui Yin, Wen-Li Zhang, Zheng Xu, Synthesis and characterization of Bi 2 S 3 faceted nanotube bundles, Solid State Communications , 2006 , 140, 116–119.

27. Xiaoping Shen, Ai-Hua Yuan, Ye-Min Hu, Yuan Jiang, Zheng Xu, Zheng Hu, Fabrication, characterization and field emission properties of large-scale uniform ZnO nanotube arrays, Nanotechnology , 2005 , 16, 2039-2043.

28. Xiaoping Shen , Song Gao, Gui Yin, Kai-Bei Yu and Zheng Xu, Crystal structure and magnetic behavior of a three-dimensional cyano-bridged assembly [CuL 1 ] 2 [Cr(CN) 6 ]ClO 4 × 0.5H 2 O (L 1 = 3,10-dipropyl-1,3,5,8,10,12-hexaazacyclo tetradecane), New Journal of Chemistry , 2004 , (8), 996-999.

29. Xiaoping Shen , Min Han, Jian-Ming Hong, Ziling(Ben) Xue, and Zheng Xu, Template-based CVD synthesis of ZnS nanotube arrays, Chemical Vapor Deposition , 2005 , 11, 250-253.

30. Xiaoping Shen , Hongjiang Liu, Xin Fan, Yuan Jiang, Jianming Hong, Zheng Xu, Construction and photoluminescence of In 2 O 3 nanotube array by CVD-template method, Journal of Crystal Growth , 2005 , 276, 471–477.

31. Xiaoping Shen , Aihua Yuan, Fei Wang, Jianming Hong, Zheng Xu, Fabrication of well-aligned CdS nanotubes by CVD-template method , Solid State Communications , 2005, 133 , 19–22.

32. Xiaoping Shen , Hong-Jiang Liu, Li Pan, Kang-Min Chen, Jian-Ming Hong, Zheng Xu, An efficient template pathway to synthesis of ordered metal oxide nanotube arrays using metal acetylacetonates as single-source molecular precursors, Chemistry Letters , 2004 , 33, 1128-1129.

33. Xiaoping Shen, Baolong Li, Jianzhong Zou, Huanming Hu, Zheng Xu, The first cyano-bridged heptanuclear Mn( III ) 6 Fe( III ) cluster: crystal structure and magnetic properties of [{Mn(salen) × H 2 O} 6 Fe(CN) 6 ][Fe(CN) 6 ] × 6H 2 O, Journal of Molecular Structure , 2003 , 657, 325-331.

34. Xiaoping Shen, Zheng Xu, Aihua Yuan, Zixiang Huang, Syntheses, crystal structures and magnetic properties of two cyano-bridged two-dimensional assemblies [Fe(salpn)] 2 [Fe(CN) 5 NO] and [ Fe(salpn)] 2 [Ni(CN) 4 ], Transition Metal Chemistry, 2004 , 29, 100-106.

35. Xiaoping Shen , Baolong Li, Jianzhong Zou, Zheng Xu, Yunpeng Yu, Shixong Liu, Crystal structure of a cyanide-bridged heptanuclear manganese( Ⅲ )-chromium( Ⅲ ) Complex with a ground state S=21/2, Transition Metal Chemistry , 2002 , 27, 372-376.

36. Xiaoping Shen , Yi-Zhi Li, Ai-Hua Yuan, Zheng Xu, A novel three-dimensional mixed bridging-ligand complex [Cu II 2 (tn) 2 ][Fe II (CN) 6 ] × H 2 O with an unexpected 1,3-diaminopropane bridge, Journal of Molecular Structure , 2005 , 754, 106-110.

37. Xiaoping Shen, A. H. Yuan, Q. J. Wu, Z. X. Huang, Z. Xu, Y. P. Yu, A new two-dimensional cyano-bridged chromium( III )-nickel( Ⅱ ) bimetallic assembly with stair-like layers, Chinese Journal of Chemistry , 2001 , 19 (6), 627-629.

38. Xiaoping Shen , J. Z. Zou, B. L. Li, H. M. Hu, Z. Xu, A novel self-assembled supramolecular complex {[Cu( II )(en) 2 ·H 2 O][Cu( I ) 2 (CN) 4 ]} n with honeycomb-like structure and its adsorption properties, Chinese Journal Chemistry , 2002 , 20, 1472-1476.

39. Aihua Yuan, Xiaoping Shen , Hu Zhou, 5,7,7,12,14,14-Hexamethyl-4,11-diaza-1,8-diazoniacyclo -tetradecane pentacyanonitrosoferrate(II) dihydrate: a supramolecular compound constructed by hydrogen bonds, Acta Cryst. C 62, 2006 , m161-m162.

40. A. H. Yuan, X. P. Shen , Q. J. Wu, Z. X. Huang, Z. Xu, Synthesis, crystal structure and magnetic properties of a two-dimensional heterometalli assembly [ Mn(salen)] 2 [Ni(CN) 4 ]?H 2 O, J. Coord. Chem. , 2002 , 55(4), 411-420.

41. B. L. Li, X. P. Shen , K. B. Yu, Z. Xu, Synthesis, structure and characterization of the cyano-bridged heteropolymer poly{[ Bis( Trimethylenediamine)copper][hexacyanocobalt]} perchlorate dihydrate with a two-dimensional framework, J. Coord. Chem. , 2002 , 55(10), 1191-1198

42. A. H. Yuan, X. P. Shen , L. D. Lu, L. Z. Chen, K. B. Yu, Synthesis, crystal structure and magnetic properties of a two-dimensional mixed-valence assembly [Fe(salen)] 2 [Fe(CN) 5 NO], Transition Metal Chem. , 2003 , 28, 163-167.

43. Y. Jiang, X. Li, Z. Xu, X. P . Shen , X. Ma, Z. L. Xue , Fabrication of monodisperse colloidal array with confinement effects, Chem. Commun. , 2006, 75-77.

44. 袁爱华, 沈小平 ,郁开北,陆路德,新型氰基桥联二维配位聚合物 [Fe(salen)] 2 [Ni(CN) 4 ] 的合成、晶体结构和磁性质, 化学学报 2003 , 61 ( 10 ), 1603-1607.

45. 袁爱华, 沈小平 ,周虎,陆路德 , (H 2 teta) 2 {[Ni(teta)][Fe(CN) 6 ] 2 }?17H 2 O (teta = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) 超分子化合物的合成、晶体结构和磁性质研究 , 化学学报 , 2005 , 63 (19), 1795-1801.

46. 沈小平 , 赵慧 , 刘琦,徐正,水热法制备 Sb2S3 纳米棒有序阵列, 无机化学学报 , 2007 , 23, 1561-1566.

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